Itheyiphu ye-PTFE yepayipi lamakhemikhali/isitsha sokunqanda ukugqwala, ukungagxili, nokuvikelwa kokuvala kudinga i-substrate ehambisanayo, isistimu yokunamathela, kanye nemidiya yamakhemikhali. I-Silicone PSA inconywa ku-200-260 ° C ngama-acids / alkali; I-acrylic PSA imelana nezinyibilikisi eziphilayo kodwa ikhawulela izinga lokushisa libe ngu-≤150°C. Ku-HF, ukubilisa >80% alkali, noma i-chlorine trifluoride, sebenzisa i-PTFE-only lining (akukho okunamathelayo okuphilayo). Okubalulekile: i-adhesive iyisixhumanisi esibuthakathaka, hhayi i-PTFE ngokwayo.

Itheyiphu ye-PTFE yobubanzi obubanzi bezinga lokushisa idinga i-silicone PSA egcina ukunamathela ukusuka -70°C kuya ku-260°C. Izakhi eziyinhloko zokuklama: ungqimba lwenguquko olunama-primer-anchored (lugwema i-delamination), i-sea-island microstructure (i-MQ resin Islands + i-polysiloxane isigaba esiqhubekayo), i-gradient crosslinking (ungqimba olungaphakathi olunomthamo omkhulu wokumelana nokukhasa, ungqimba lwangaphandle olunobukhulu obuphansi bokudonswa kwezinga lokushisa eliphansi), kanye nezigcwali ezizinzile ze-oxid oxide (i-oxid oxide). Amasegimenti e-phenyl-modified siloxane acindezela i-crystallization yezinga lokushisa eliphansi, evumela ukuguquguquka okungaphansi -100°C.

Ngesikhathi sokumbozwa kwetheyiphu ye-PTFE, izinga le-solvent volatilization ye-adhesive ezwela ukucindezela kwe-silicone iyipharamitha yenqubo ebalulekile. Kushesha kakhulu → ukuhlikihlwa kwesikhumba, ukungaleveli kahle, amaphinifa (i-solvent evalelekile), nama-craters (ukujiya noma okubangelwa ukungcola). Iyanensa kakhulu → ukuwohloka, imiphetho ewugqinsi, kanye nokumanzisa ku-PTFE yamandla aphansi. Isu elilungile: ukuvuthwa kancane kwasekuqaleni kokulinganisa nokuphunyuka kwebhamuza, bese kusheshiswa ukomiswa ukuze kubunjwe. Sebenzisa izincibilikisi ezixubile (i-toluene/xylene + ukomisa ngokushesha) nezinga lokushisa likahhavini we-gradient (eliphansi→elimaphakathi→phezulu).

Itheyiphu ye-PTFE yokushisa okuphezulu ilahlekelwa ukunamathela ngemva kokusetshenziswa okuphindaphindiwe ngenxa yokungcoliswa kwendawo (uthuli, uwoyela we-silicone), ukwehluleka kokunamathela okunamathelayo (insalela), noma ukubopha okubuthakathaka kwe-substrate. Izisombululo: i-silicone ye-high-crosslink i-PSA (ukufuduka okuphansi, i-balance tack/amandla okubamba), ukwelashwa kwe-primer ku-PTFE substrate, ukusekelwa kwe-fiberglass ecinene, nokubamba okufanele (indawo ehlanzekile, ikhasi elipholile, i-engeli engu-180°). Ukuhlolwa komthamo kuqinisekisa ukuthuthuka.

Amateyipu e-PTFE okushisa okuphezulu agcinwe efomini lokugoqa angahlushwa ukunamathela kwe-interlayer (ukuvinjwa) kanye nokudluliselwa okunamathelayo ohlangothini olunganamathele. Imbangela: PTFE ifilimu inkumbulo nokunwebeka futhi abicah PSA creep ngaphansi kwengcindezi nokushisa. Isixazululo: I-gradient winding tension - iqinile ezingqimbeni ezingaphandle, iyaxega ezingqimbeni zangaphakathi - kusetshenziswa isilawuli sokuqina sokuqina kwe-loop. Ihambisana ne-coating yokukhishwa, isitoreji esifanele (15-40°C, 30-70% RH), ukubekwa okuvundlile, nokuzungezisa kwekota.

Itheyiphu yezinga lokushisa eliphezulu ye-PTFE esetshenziswa ekuthintaneni nokudla kufanele ihloniphe imikhawulo eqinile yezinga lokushisa: ≤260°C ukuze isetshenziswe ngokuqhubekayo (akukho mkhawulo wesikhathi), 260-300°C kufika kumaminithi angu-30 kuphela, futhi >300°C kunqatshelwe. Itheyiphu eyokuthintana nabantu abangaqondile kuphela (ama-tray liners, amakhava okushisa), hhayi ukugoqa ukudla okuqondile. Ungalokothi usebenze ngaphandle komthwalo wokudla (ukushisa okomile). Shintsha uma enamabhamuza, aphuzi, noma agugile.

Izinamathiselo ezizwela ukucindezela kwe-Silicone (PSA) zamateyipu we-PTFE wezinga lokushisa eliphezulu ziyahlukahluka kakhulu ekusebenzeni kokuguga okuphezulu kwezinga lokushisa. I-Methylphenyl silicone PSA igcina >85% amandla ekhasi ngemva kwezinsuku ezingu-250°C/7, kuyilapho uhlobo lwe-methyl olujwayelekile lwehla luye ku-50-70%. Izinhlelo ze-addition-cured (hydrosilylation) zinikeza ukuzinza okungcono kakhulu kunokwelashwa nge-peroxide. Ngesevisi eqhubekayo engu-200°C+, khetha amamaki e-phenyl aphezulu alaphelwe ngokwengezwa.

Amateyipu e-PTFE anamathela ngokushisayo (i-PSA) kufanele aqhube ukushisa ngenkathi enamathela. Ukwengeza ama-filler kuthuthukisa ukuqhutshwa kokushisa kodwa kulimaza ukunamathela. Ibhalansi ekahle isebenzisa izinhlayiya eziyindilinga ezimahhadla (njengohlaka lwamathambo) oluhlanganiswe nezinhlayiya ezinhle (ukugcwalisa izikhala), okugcina isamba silayishwa ngaphezu nje komkhawulo we-percolation. Gwema ama-flakes nama-fibers; babulala i-tack.

Itheyiphu ye-PTFE yokushisa okuphezulu isebenzela imboni ye-PV ngezindima ezimbili ezihlukene: inqubo esebenzisekayo (ivimbela ukunamathela okuchichima kwe-EVA kuma-laminator, imaski ye-solder) kanye nokufakwa kwempilo ende (ukugoqa kwebhasi, ukulungiswa kwebhokisi lokuhlangana). Ngokusetshenziswa kwangaphakathi unomphela, amateyipu kufanele adlule ku-IEC 61215: ukushisa okumanzi okungu-1000-2000h, i-UV, ukuhamba ngebhayisikili okushisayo (-40°C kuya ku-+85°C), ne-silicone PSA kanye nokuncipha kuka-<1%.

Itheyiphu ye-PTFE yokushisa okuphezulu esetshenziswa emimeseni evala ukushisa nemicu yokuvala iletha amanani amane abalulekile: ivimbela ukunamathela kwepulasitiki okuncibilikisiwe (iqeda isikhathi sokuphumula), ivikela ukufa kokuvalwa okumba eqolo, yenza kube lula ukushisa/ingcindezi yezivalo ezingaguquki, futhi inciphisa ukungqubuzana kwefilimu. Kunconywa itheyiphu ye-Fiberglass-backed (0.13-0.25 mm) ene-silicone PSA (≥260°C). I-Anti-static black tape yemigqa enesivinini esikhulu.