Views: 0 Author: Site Editor Publish Time: 2026-07-23 Origin: Site
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PTFE (Polytetrafluoroethylene) starts decomposing at approximately 400 °C. Exposed to nearly 3,000 °C combustion gas from engines, it rapidly depolymerizes into tetrafluoroethylene monomers. This chemical bond cleavage is a highly endothermic reaction. Each kilogram of material absorbs substantial heat, converting high-temperature thermal energy into internal gas energy and effectively extracting heat from the wall surface.
As analyzed by Jiangsu PTFE high-temperature cloth manufacturers, this phase change and endothermic decomposition process forms an active cooling barrier on the surface of the thermal insulation layer. It drastically reduces the heat flux conducted to the metallic engine housing and prevents strength loss of the housing caused by excessive temperature.
Large volumes of gases such as tetrafluoroethylene generated by PTFE decomposition permeate outward through micro-pores on the insulation layer surface like transpiration under pressure. This mass ejection process removes abundant surface heat and delivers forced cooling.
The escaping gases accumulate on the wall to form a flowing gas film that isolates high-temperature combustion gas from the wall. This gas film features extremely high thermal resistance and significantly weakens convective heat transfer. Experiments prove it can reduce near-wall heat flux density by more than 50%.
The gas film modifies velocity and temperature distribution within the boundary layer, greatly alleviating direct impact and friction of two-phase flow containing metallic particles such as aluminum against the wall and restraining mechanical ablation.
After PTFE pyrolysis, residues form a porous carbonaceous structure attached to undecomposed material. This char layer features a 3D network skeleton and maintains certain structural continuity.
As noted by Jiangsu PTFE high-temperature cloth manufacturers, filled with enclosed voids, the char layer possesses far lower thermal conductivity than the original rubber matrix, down to the magnitude of 0.1 W/(m·K). It acts as a major barrier to heat conduction and slows inward heat propagation within the layer.
Though porous, the char layer can withstand certain aerodynamic shear stress, guaranteeing integrity of the thermal insulation structure and shielding deep-layer materials from intense thermal shock during long-duration operation.
PTFE itself exhibits an ultra-low friction coefficient (~0.04). Filled into the ablation liner, it remarkably lowers frictional shear induced by high-speed particle-laden gas flow, reduces mechanical erosion, and prevents the insulation layer from being "thinned by gas scouring".
Its decomposition proceeds steadily and controllably, featuring low ablation rate and good char-forming performance. The insulation layer is consumed slowly and evenly, sustaining effective thickness for extended periods and avoiding housing overheating failure caused by local burn-through.
According to Jiangsu PTFE high-temperature cloth manufacturers, in practical engineering, micron-sized PTFE powder is filled into flexible matrices such as EPDM (Ethylene-Propylene-Diene Monomer) rubber and NBR (Nitrile Butadiene Rubber). Combustion chamber insulation liners and propellant grain cladding layers are fabricated via mould pressing or winding processes. These products are widely adopted in solid rocket motors of surface-to-air, anti-ship and other tactical missiles as well as space launch vehicles to secure structural thermal protection.
The above information is provided by Jiangsu Aokai New Materials Technology Co., Ltd.
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