Ekiwandiiko kino kyetegereza enkola y’ekika kya platinum catalyst n’okusengejja ku crosslinking kinetics ya addition-cure silicone rubber. Ebika by’ekirungo ekiziyiza: Ekirungo kya Speier (chloroplatinic acid, Pt4+) kyetaaga okukendeeza ku bika ebikola ebya valenti entono, nga kikola nga ekirungo ekisookerwako; Ekirungo kya Karstedt (Pt0 nga kiriko divinyltetramethyldisiloxane) kiyingira butereevu mu nsengekera y’ekirungo ekiziyiza. Ebikolwa eby’ekika: Speier alaga ekiseera ky’okuyingiza ekimanyiddwa nga S-shaped curing curve (empola nga bukyali, eyanguwa oluvannyuma) n’amasoboza ag’okukola agalabika aga waggulu; Karstedt alaga tewali induction, high initial rate nga sharp exotherm, activation energy eya wansi.

Ekiwandiiko kino kikwata ku mikisa egisobola okukozesebwa ku lugoye lwa Teflon olw’ebbugumu eringi mu makolero ga bbaatule ez’embeera enkalu ezigenda zikula. Ebitundu bina: Dry electrode/electrolyte membrane manufacturing — emisipi egy’ebbugumu eringi egy’okuziyiza emiggo egy’okunyiga emizingo egy’ebbugumu (150-250°C) okusobozesa okusekula obulungi firimu ezeewanirira; layer ebikka roller eyokya nga semi-permanent anti-stick layer; okukakasa nti firimu eweweevu ku ngulu, ekendeeza ku bulema, alongoosa amakungula. Release liners ne cushioning pads for hot-pressing densification — bbaatule za sulfide/polymer zeetaaga okunyiga okw’ebbugumu isostatic/flat (100-300°C, makumi ga MPa); Olugoye lwa PTFE oluteekeddwa wakati wa bbaatule stack n’ekikuta luziyiza okunywerera, lusobozesa okugabanya puleesa mu ngeri y’emu nga luyita mu micro-elasticity, lukuuma ebipande ebibugumya.

Ekiwandiiko kino kikwata ku kukwatagana okw’omuwendo wakati w’ekitundu kya gel n’amaanyi g’okukwatagana mu bisiiga ebiwulikika ku puleesa ya silikoni ku Teflon tape. Ekitundu kya ggelu = ebitundu by’obuzito ku kikumi eby’omukutu ogusalasala ogutasaanuuka mu toluene (Soxhlet extraction, 24hr). Amaanyi agakwatagana agamanyiddwa olw’amaanyi agakwata ku bbugumu erya waggulu (180°C, 1kg). Ranges ssatu: wansi w’ensonga enkulu (<60%) — tewali mutimbagano ogukulukuta, ogukwata amaanyi okumpi ne ziro; practical range (60-85%) — amaanyi agakwatagana gakula mu ngeri ey’ekitalo n’ekitundu kya gel, 60%→70% gasitula obudde bw’okukwata okuva ku ddakiika okutuuka ku ssaawa, 70%→80% kiwa okweyongera kwa 3-10x; high crosslinking (>85%) — amagoba mpola (85%→95% 20-50% zokka okweyongera), tack egwa nnyo, >95% efiirwa eby’obugagga bya PSA.

Ekiwandiiko kino kyetegereza enkyukakyuka mu njegere za molekyu za PTFE wansi w’obusannyalazo bwa ultraviolet. Main-chain scission n’okukendeeza ku buzito bwa molekyu: UV (254nm, 471 kJ/mol) emenya CC bonds (347 kJ/mol), ekivaako homolysis, okukola CF2-terminated free radicals, okukendeera kw’obuzito bwa molekyu mu ngeri ey’amaanyi, okufiirwa obugumu n’okuwanvuwa. Amakubo g’ensengekera ya free radical: mu oxygen, peroxy radicals zitondebwa, nga ziddamu okusengeka okutuuka ku bibinja by’enkomerero bya acyl fluoride (—COF) ne carboxylic acid (—COOH), ne zifulumya COF2 ne CO2 (COF2 esengejja amazzi okutuuka ku HF); mu mpewo ezitakola, obutagerageranyo/okuddamu okugatta kwe kufuga, naye okusalasala kw’enjegere kusigala nga kwe kusinga.

Ekiwandiiko kino kikwata ku kusiiga olugoye lwa Teflon olw’ebbugumu eringi mu layeri eziziyiza ebbugumu mu spacesuit. Ekintu ekikulu: Olugoye lwa fiberglass olusiigiddwa PTFE, olumanyiddwa mu by’omu bbanga nga Beta cloth, nga lugatta okukyukakyuka kw’olugoye ne PTFE extreme-environment inertness. Omulimu: oluwuzi olw’ebweru ennyo olwa Thermal Micrometeoroid Garment (TMG) mu yuniti z’okutambula ebweru w’emmotoka, ezitunudde butereevu mu vacuum, enjawulo z’ebbugumu ezisukkiridde, ne micrometeoroids ng’ekiziyiza ekisooka eky’omubiri/ebbugumu eri firimu ez’omunda eziriko aluminiyamu. Obukuumi bw’obutonde obw’ekitalo: bugumira -200°C okutuuka ku +260°C (etunudde enjuba >120°C okutuuka ku kisiikirize -160°C); enjuba enjeru eraga emisinde gy’enjuba; ekuuma firimu za polyimide ezitali nnywevu ezikoleddwa mu aluminiyamu okuva ku kukunya n’okukutuka. Obuyambi bw’entambula: okusikagana okutono PTFE kungulu kuziyiza layer tangling mu kiseera ky’okubeebalama kw’ekiyungo, okukakasa EVA flexibility.

Ekiwandiiko kino kikwata ku birungi by’okukozesa olugoye lwa Teflon olw’ebbugumu eringi mu kukala kwa bbaatule ya lithium electrode. Ekozesebwa nga conveyor belts oba oven liners, okugonjoola ebizibu bisatu ebikulu: slurry adhesion, corrosion, ne electrode scratching. Ebitundu bina ebirungi: Omutindo gw’obusannyalazo n’amakungula — eby’obugagga ebiziyiza omuggo biziyiza okunywerera kwa PVDF binder okusobozesa okwangu okusekula okujjuvu; obutambuzi bw’ebbugumu obw’enjawulo ku 100-140°C buziyiza okwatika/okwokya; ekifo ekiweweevu kimalawo okukunya n’okuyiwa pawuda; Okuwangaala n’okutebenkera mu kukola — okuziyiza eddagala eri NMP solvent ne electrolyte vapors awatali kuzimba/kukaddiwa; amaanyi g’okusika amangi n’okutebenkera kw’ebipimo okuva mu fiberglass substrate okusobola okuteeka mu kifo ekituufu; okuyonja okwangu nga temuli bisigadde bitono bw’ogeraageranya n’emisipi egy’ekyuma egy’akatimba.

Ekiwandiiko kino kikwata ku ngeri y’okukwataganyaamu ebbugumu ly’okuvunda n’ekitundu ky’obulamu bw’ebirungo ebisalasala perokisayidi (BPO ne DCP) n’eddirisa ly’enkola y’okuwonya erya Teflon tape. Core data: BPO — 1-eddakiika ekitundu-obulamu ku ~ 131 ° C, 1-hr ku ~ 92 ° C, 10-hr ku ~ 72 ° C; DCP — eddakiika emu ku ~ 171 ° C, essaawa emu ku ~ 135 ° C, essaawa 10 ku ~ 115 ° C. Ensonga y’okukwatagana: ekyesiiga kyetaaga 97-99% crosslinking = 5-7 half-lives; obudde bw’okuwona = 5-7 × ekitundu ky’obulamu ku bbugumu erigendererwa. Back-calculate ebbugumu okuva ku production line residence time oba back-calculate obudde okuva ku maximum allowable temperature.

Ekiwandiiko kino kikwata ku sipiidi ya layini eya bulijjo ku layini y’okufulumya olugoye olw’ebbugumu eringi olwa PTFE. Sipiidi eya bulijjo: 2-15 m/min, stable operating range 3-8 m/min, emifaliso emigonvu/layini ez’amaanyi okutuuka ku 10-15 m/min. Ebiziyiza okuva mu kuyingira kw’okufukirira: olugoye lulina okuba nga lujjudde mu bujjuvu ne PTFE emulsion mu fiber bundle interiors — sipiidi ey’amaanyi ennyo ereeta okufukirira okutamala, enjala ya resin n’ebiwuzi ebikalu; emulsion viscosity, solids concentration, fabric weave density byonna bikendeeza ku sipiidi y’okuyingira, ekyetaagisa emisinde empola ku lugoye enzito/olunene. Okuyita mu kusiiga: okuyita okungi (2-6+) okwetaagisa okusiiga okunene okutaliimu buzibu; okusooka okuyita mpola okusimba ennanga, okuyita okuddirira kuyinza okwongerwako mu kigero.

Ekiwandiiko kino kigeraageranya enjawulo wakati w’okubuguma kw’amasannyalaze aga infrared n’okubuguma kw’okutambula kw’empewo eyokya ku crosslinked structure uniformity of silicone adhesive layer. Enkola z’okutambuza ebbugumu: empewo eyokya ye convection-conduction, gentle era egenda mu maaso, ekola ebbugumu ery’ekigero; IR ye radiation-absorption nga erimu okunyiga okw’amaanyi ku ngulu (micrometers to millimeters) okutondawo steep surface-to-interior gradient. Ebikosa ku nsasaanya ya density y’okusalasala: empewo eyokya esobozesa ebitundu eby’omunda n’eby’ebweru okuyingira mu bbugumu ly’okuwunyiriza kumpi mu kiseera kye kimu, okuvaamu density y’okusalasala ey’enjawulo okuyita mu buwanvu; IR ereetera layeri y’okungulu okuwona amangu ddala nga ekola olususu olunene olulemesa okutambuza ebbugumu, ekivaamu sharp gradient of crosslink density okukendeera okuva kungulu okudda munda.

Ekiwandiiko kino kikwata ku silika ebirimu n’engeri y’okukozesaamu olugoye olw’obuwuzi bw’endabirwamu olulimu silika omungi. Silica content specification: core indicator is SiO2 ≥96% (omutindo 96-98%, premium grades >99% okuyita mu acid leaching ne sintering, okusemberera pure quartz fiber). Okukola: Olugoye lwa E-glass luyita mu kusengejja asidi ayokya okusaanuusa ebitundu ebitali bya silika (boron oxide, sodium oxide), ne lukola amagumba agalimu obutuli aga silika omungi, oluvannyuma ne gasiigibwa okusobola okufuuka densification. Ebirungi ebikulu: okuweereza okutambula obutasalako ku 900°C mu bbanga erikola oxidizing, mu bbanga ettono waggulu wa 1200°C, ekifo ekigonvuwa okumpi ne 1700°C; okutebenkera kw’eddagala ku asidi/alkali ezisinga obungi okuggyako HF ne asidi wa phosphoric ayokya; obutakyukakyuka bwa dielectric obutono n’okuziyiza okunywevu ku bbugumu erya waggulu.