Sengoliloeng sena se hlahloba tšusumetso ea mofuta oa li-catalyst tsa platinum le ho tsepamisa mohopolo ho crosslinking kinetics ea rabara ea silicone ea tlatsetso. Mefuta ea Catalyst: Speier catalyst (chloroplatinic acid, Pt⁴⁺) e hloka phokotso ho mefuta e sebetsang e tlaase, e sebetsang e le precatalyst; Karstedt catalyst (Pt⁰ e nang le divinyltetramethyldisiloxane) e kena ka ho toba potolohong ea catalytic. Litlamorao tsa mofuta: Speier e bonts'a nako ea induction e nang le sebopeho sa S-curing curve (e liehang pele, e potlakisa hamorao) le matla a holimo a bonahalang a ts'ebetso; Karstedt ha e bonts'e induction, sekhahla se phahameng sa pele se nang le exotherm e bohale, matla a tlase a ts'ebetso.

Sengoliloeng sena se akaretsa menyetla ea ts'ebeliso ea lesela la mocheso o phahameng oa Teflon indastering e hlahang ea betri ea boemo bo tiileng. Libaka tse 'nè: Ho etsa li-membrane tsa electrode / electrolyte tse omileng - mabanta a conveyor a mocheso a phahameng a mocheso o thibelang lithupa bakeng sa ho hatisa hot roll (150-250 ° C) ho nolofalletsang ho peeling boreleli ba lifilimi tse ikemetseng; hot rolara kwahelang lera e le seka-ka ho sa feleng-ba khahlanong le thupa lera; e tiisa bokaholimo ba filimi e boreleli, e fokotsa liphoso, e ntlafatsa chai. Lokolla li-liner le li-cushioning pads bakeng sa densification e chesang e chesang - libeteri tsa sulfide / polymer li hloka ho hatelloa ha isostatic / flat flat (100-300 ° C, mashome a MPa); Lesela la PTFE le behiloeng pakeng tsa stack ea betri le hlobo le thibela ho khomarela, le nolofalletsa ho ajoa ha khatello e tšoanang ka micro-elasticity, ho sireletsa lipoleiti tse futhumatsang.

Sengoliloeng sena se akaretsa mangolo a mangata pakeng tsa karoloana ea gel le matla a kopantsoeng ka har'a likhomaretsi tse sa utloeleng khatello ea silicone bakeng sa tepi ea Teflon. Karolo ea gel = karolo ea boima ba marang-rang a marang-rang a sa tsitsang ka toluene (Soxhlet extract, 24hr). Matla a kopanetsoeng a khetholloang ke matla a ho tšoara mocheso o phahameng (180 ° C, 1kg). Mekhahlelo e meraro: ka tlase ho ntlha ea bohlokoa (<60%) - ha ho marang-rang a percolating, a tšoereng matla haufi le zero; mefuta e sebetsang (60-85%) - matla a momahaneng a ntse a hōla ka sekhahla ka karoloana ea gel, 60% → 70% e phahamisa nako ea ho tšoara ho tloha metsotso ho ea ho lihora, 70% → 80% e fana ka keketseho ea 3-10x; high crosslinking (> 85%) - phaello butle (85% → 95% feela 20-50% e eketseha), tack e theoha haholo,> 95% e lahleheloa ke thepa ea PSA.

Sengoliloeng sena se hlahloba liphetoho ho liketane tsa limolek'hule tsa PTFE tlas'a mahlaseli a ultraviolet. Main-chain scission le phokotso ea boima ba limolek'hule: UV (254nm, 471 kJ/mol) e roba bond CC (347 kJ/mol), e bakang homolysis, e hlahisa li-radicals tsa mahala tse felisitsoeng ke CF₂, ho theoha ho matla ha limolek'hule, tahlehelo ea boima le bolelele. Litsela tsa mahala tsa radical reaction: ka oksijene, li-peroxy radicals li theha, ho hlophisa bocha ho acyl fluoride (-COF) le lihlopha tsa ho qetela tsa carboxylic acid (-COOH), ho lokolla COF₂ le CO₂ (COF₂ hydrolyzes ho HF); libakeng tse sa sebetseng, ho se leka-lekane / ho kopanngoa hoa busa, empa ketane scission e ntse e le eona e ka sehloohong.

Sengoliloeng sena se akaretsa ts'ebeliso ea lesela la mocheso o phahameng oa Teflon ka har'a sepakapaka sa mohatsela oa mocheso. Lintho tse bonahalang: Lesela la fiberglass le koahetsoeng ke PTFE, le tsejoang sebakeng sa sefofane e le lesela la Beta, le kopanyang ho feto-fetoha ha lesela le PTFE e feteletseng-tikoloho inertness. Karolo: karolo e ka ntle ea Thermal Micrometeoroid Garment (TMG) ka li-unit tsa motsamao tsa extravehicular, tse shebaneng ka kotloloho le vacuum, phapang e feteletseng ea mocheso, le li-micrometeoroids e le tšitiso ea pele ea 'mele / mocheso bakeng sa lifilimi tse ka hare tsa aluminium. Tšireletso e feteletseng ea tikoloho: e mamella -200 ° C ho ea +260 ° C (e shebaneng le letsatsi> 120 ° C ho ea moriting -160 ° C); bokaholimo bo bosoeu bo bonahatsa mahlaseli a letsatsi; e sireletsa lifilimi tse senyehang tsa aluminium tsa polyimide ho tsoa mengopeng le meokhong. Thuso ea ho sisinyeha: khohlano e tlase ea PTFE e thibela ho tsitsinyeha ha lera nakong ea ho kobeha ha manonyeletso, ho netefatsa hore EVA e fetoha le maemo.

Sengoliloeng sena se akaretsa melemo ea ts'ebeliso ea lesela la Teflon le mocheso o phahameng ka ho omisa li-electrode tsa lithium. E sebelisoa e le mabanta a conveyor kapa liner tsa ontong, e rarolla mathata a mararo a mantlha: slurry adhesion, corrosion, le electrode scratching. Libaka tse 'nè tsa melemo: Boleng ba Electrode le lihlahisoa - thepa ea anti-stick e thibela ho khomarela PVDF binder e nolofalletsang ho peeling ho feletseng habonolo; conductivity e tšoanang ea mocheso ho 100-140 ° C e thibela ho phunyeha / ho chesa; bokaholimo bo boreleli bo felisa mengopo le phokotseho ea phofshoana; Ho tšoarella le botsitso ba ts'ebetso - khanyetso ea lik'hemik'hale khahlanong le mouoane oa NMP le mouoane oa electrolyte ntle le ho ruruha / botsofali; matla a phahameng a tsitsipano le botsitso ba sebopeho ho tsoa ho fiberglass substrate bakeng sa boemo bo nepahetseng; ho hloekisa habonolo ka masala a fokolang ha ho bapisoa le mabanta a tšepe.

Sengoliloeng sena se akaretsa mokhoa oa ho bapisa mocheso oa ho bola le halofo ea bophelo ba li-agent tsa peroxide crosslinking (BPO le DCP) le fensetere ea ts'ebetso ea ho folisa bakeng sa tepi ea Teflon. Lintlha tsa mantlha: BPO - 1-min halofo ea bophelo ho ~ 131 ° C, 1-hora ho ~ 92 ° C, 10-hr ho ~ 72 ° C; DCP — 1-mots ho ~171°C, 1-hr ho ~135°C, 10-hr ho ~115°C. Matching logic: sekhomaretsi se hloka 97-99% crosslinking = 5-7 halofo ea bophelo; ho folisa nako = 5-7 × halofo ea bophelo ka mocheso oa sepheo. Ka morao-bala mocheso ho tloha moleng oa tlhahiso ea nako ea bolulo kapa nako ea ho khutlela morao ho tloha mocheso o phahameng o lumelletsoeng.

Sengoliloeng sena se akaretsa lebelo le tloaelehileng la lebelo bakeng sa mohala oa tlhahiso ea lesela la PTFE le mocheso o phahameng oa mocheso. Lebelo le tloaelehileng: 2-15 m / min, sebaka se tsitsitseng sa ts'ebetso ea 3-8 m / min, masela a mosesaane / mela e phahameng ho fihlela ho 10-15 m / min. Litšitiso tsa ho kenella ho kenella: lesela le tlameha ho tlala ka botlalo ka PTFE emulsion ho kena ka har'a li-fiber bundle insides - lebelo le phahameng haholo le baka ho se lekane ho kenngoa, tlala ea resin le likhoele tse omeletseng; emulsion viscosity, solids concentration, lesela la weave density kaofela li fokotsa sekhahla sa ho kenella, tse hlokang lebelo le tlase bakeng sa masela a teteaneng / a teteaneng. Liphasete tsa ho roala: li-passes tse ngata (2-6+) tse hlokahalang bakeng sa ho roala ho se nang sekoli; pele ho feta butle bakeng sa ho anchoring, liphase tse latelang li ka eketseha ka mokhoa o itekanetseng.

Sengoliloeng sena se bapisa liphapang lipakeng tsa ho futhumala ha mahlaseli a infrared le ho futhumala ha moea o chesang ka har'a sebopeho se kopaneng sa sebopeho sa sekhomaretsi sa silicone. Mekhoa ea ho fetisa mocheso: moea o chesang ke convection-conduction, o bonolo ebile o tsoela pele, o etsa mocheso o itekanetseng oa mocheso; IR ke ho monya mahlaseli ka ho monya ka matla holim'a metsi (li-micrometer ho isa ho limilimithara) ho theha moepa o moepa ho tloha holimo ho ea ka hare. Liphello holim'a phepelo ea li-crosslink density: moea o chesang o lumella likarolo tse ka hare le tse ka ntle hore li kene ka har'a mocheso oa vulcanization hoo e batlang e le ka nako e le 'ngoe, ho fana ka li-uniform crosslink density hammoho le botenya; IR e etsa hore bokaholimo bo folise hang-hang ho theha letlalo le teteaneng le sitisang phetiso ea mocheso, e leng se bakang hore sekhahla se matla sa crosslink se fokotsehe ho tloha holimo ho ea kahare.

Sengoliloeng sena se akaretsa litaba tsa silika le maemo a ts'ebeliso ea lesela la fiber e phahameng ea silika. Tlhaloso ea litaba tsa silika: pontšo ea mantlha ke SiO₂ ≥96% (e tloaelehileng 96-98%, litekanyetso tsa premium> 99% ka acid leaching le sintering, e atamelang fiber e hloekileng ea quartz). Tlhahiso: Lesela la E-glass le kena ka har'a asiti e chesang ho qhaqha likarolo tseo e seng tsa silika (boron oxide, sodium oxide), ho etsa skeleton e nang le porous high-silica skeleton, ebe e siloa bakeng sa densification. Melemo ea mantlha: ts'ebeletso e tsoelang pele ho 900 ° C libakeng tse nang le oxidizing, nako e khuts'oane ka holimo ho 1200 ° C, sebaka sa ho nolofatsa haufi le 1700 ° C; botsitso ba lik'hemik'hale khahlanong le li-acids / alkali tse ngata ntle le HF le hot phosphoric acid; li-insulation tsa dielectric tse tlaase le tse tsitsitseng ka mocheso o phahameng.