This article compares room-temperature and high-temperature maturation of silicone pressure-sensitive adhesive for PTFE tape. High-temperature maturation (120-180°C) creates dense crosslinked networks with strong cohesive strength, preventing adhesive residue after peeling. It forms chemical anchoring bonds with PTFE substrates via primer co-curing, eliminating delamination risks. High-temperature maturation also removes low-molecular volatiles before delivery, preventing bubbling and silicone oil contamination during first heating.