Views: 0 Author: Site Editor Publish Time: 2026-07-14 Keeb Kwm: Qhov chaw
Cov Lus Qhia
ThemanufactureradoptsMQsiliconeresinasthecoretackifierandreinforceingagent, nceMQ/gumratioto1.2:1–2:1(cov qhab nia siab tshaj qhov sib txawv).ThishighMQratioformscontinuous rigid'hard-phase'microdomainswithinheadhesivelayer, uas constrainthemovement ofsiloxanechainsegmentsandsubstantiallyimprovethestoragemodulusandcreepresistanceatetemperatures.
Phenyl, diphenyl, orcarboranegroups tau qhia txog cov pob txha polydimethylsiloxanebackbone (piv txwv li, 20-30mol% phenyl ntsiab lus) mus rau sab nraud ntawm lub tshuab hluav taws xob thiab txhawb nqa ob lub iav hloov mus rau qhov kub thiab txias. rmaldecompositiontemperature.Thecrosslinkingsystempreferentiallyemploysaddition-kurehydrosilylation(Pt-catalyzed), tsim-C-C-los-Si-C-crosslinkingbridgeswithsuperiorthermalstability.
Bypreciselyadjustingtheactivehydrogen contentandchainlengthofthehydrogen-containingsiliconeoil, txheeb zesmallanduniformMc(kwv yees li 5,000–15,000g/mol) tau ua tiav, xyuas kom meej tias kev ua haujlwm tau zoo dua qub txawm tias muaj kev kub ntxhov.Extendedpost-curingorhigh-temperatureannealingisappliedtoconsumeresidualreactivegroupsandreducestressrelaxationcausedbynetwork defects.
1.Primer-anchoringlayer(1–3μm): Siv sasilanecouplingagent uas muaj epoxyoracryloyloxygroups, pre-polymerizedwithMQresin, toprovidebothchemicalbondingtothePTFEsubstrateandco-crosslinkingwiththeuppersiliconelayer.
2.High-moduluscohesivelayer(mainbody, approx.30–50μm): Useshigh-MQ-ratio, siab-phenyl-cov ntsiab lus, high-crosslink-densitysiliconeadhesivetofurnisharobustshear-resistantskeleton.
3.Viscoelasticfunctionallayer(incontactwiththeadherend,3–8μm): Ua haujlwmlow-MQ-ratioorhydroxy-terminatedsilicone-oil-modifiedsoftsiliconeadhesivetolowersurfacemodulusandensurerapidwettingandconformability totheadherendateelevatedtemperatures.
Themanufacturerusesfumedsilica(specificsurfacearea200–380m²/g), deg-treated withvinyltriethoxysilaneorhexamethyldisilazane, ataloadingof10–25wt%. reversiblephysicalcrosslinkingnetwork uasdissipatesenergyandpreventsmolecular chainslippageathightemperatures.High-shardispersionensures tiasthesilicaexistsas'clusters'withagglomeratesizesbelow100nm,avoidingstressconcentration.
Ntxiv ntawm 1–5wt% ob peb-layergrapheneororgano-modifiednano-montmorillonite, uas yog cov chaw tsim khoom lag luam, uas yog cov txheej txheem tsim los ntawm cov txheej txheem ntawm kev sib tsoo-inducedalignmentduringcoating, formsa'mazeeffect'paralleltothetapep txoj kab, qhov tseem ceeb nce ntxiv kev tiv thaiv tomolecular chainmotioninthesheardirection.Graphenealsooffersexcellentthermalconductivity, txo covhotspotsintheadhesivelayeranddelayingthermalsoftening.
PTFEsurface yog thawj zaug kho nrog asodium-naphthalene-THFsolutionorlow-pressureargon/oxygenplasmatogenerateanactivatedlayer uas muaj carboxylandhydroxylgroups.Aprimersolution muaj bifunctionalmolecules (piv txwv li, isocyanatesilane, titanatecoupling) ated.Oneendoftheprimerreactswith–OH/–COOHonthePTFEsurface,whiletheotherendparticipatesinhydrosilylationorcondensationcrosslinkingwiththesiliconeadhesive,formingachemicalbondnetworkthat penetratestheinterface.Thisapproachcanincreasepowerhigh-temperatures5°-temperatureholding
Arampedcuringprofileisemployed: ua ntej, cov kuab tshuaj sarredrivenoffandtheadhesivelayerisleveledat80–100°C; thenhydrosilylationanddensepackingofMQresinarecompletedat150–170°C; kawg,post -curingiscarriedoutat200-220 ° C rau ntau lub sijhawm ua haujlwm tshem tawm cov kev ntxhov siab hauv lub cev thiab ua kom lub cev tsis muaj zog sib txuas cov ntsiab lus.Slowcoolingpreventsmicrocrackingduetodifferentialthermalshrinkage.
Cov ntaub ntawv saum toj no yog muab los ntawmJiangsuAokaiNewMaterialTechnology Co., Ltd.
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